The most effective registered chemical alternative to methyl bromide plus chloropicrin fumigation for the control of pathogens, nematodes, and weed seeds is either
- chloropicrin mixed with 1,3-dichloropropene (InLine) followed by metam sodium or
- chloropicrin alone followed by metam sodium
Because chloropicrin and 1,3-dichloropropene are less volatile than methyl bromide, they can be applied to raised beds through drip irrigation systems and have been shown to be effective in controlling soilborne pathogens and most weed seeds, resulting in comparable strawberry yields. However, applying these materials through drip systems does not control the pathogens in the edges of raised beds.
Currently, over 55% of the California strawberry acreage is drip fumigated. Drip fumigation is convenient because workers are not required to be in the field during application. However, successful drip fumigation requires adequate soil preparation, a well-designed drip irrigation system, dependable chemigation equipment, well-laid plastic tarp, and timeliness of the process to accommodate longer plantback time.
Soil Preparation
As with all soil fumigation, the first step is to properly prepare and till the soil. Current soil preparation and bed listing practices used after methyl bromide fumigation are generally adequate. Following this, firmly pack the beds and eliminate any dirt clods. If the soil is dry, it may be necessary to preirrigate with enough water to initiate weed seed germination (1–1.5 acre-inch).
Uniform water distribution is necessary in a drip irrigation system and is easiest to obtain on fairly level terrain. On steep or hilly fields, create beds that follow soil contour lines at grades that do not exceed 4 feet uphill or 8 feet downhill from the beginning of the drip line.
When laying the plastic tarp, remove any shanks or chisels to avoid creating channels in the soil, which can result in poor water and fumigant distribution in the soil bed. Repair any holes or tears in the plastic tarp. Avoid embossed tarps to reduce loss of fumigants through volatilization. The use of totally impermeable film (TIF) will enhance weed control in the bed. However, TIF holds fumigants in the soil for longer periods than the standard tarp, so a longer plantback time or bed ventilation for 2 weeks before planting may be required (refer to the pesticide label).
Amount of Water
If chloropicrin or 1,3-dichloropropene is applied at the same time as metam sodium, they react and rapidly degrade in the irrigation water. Instead, they should be applied sequentially with the first application consisting of 1,3-dichloropropene plus chloropicrin or chloropicrin alone followed 5 to 7 days later with an application of metam sodium. Applying the pesticides in this order helps to maximize their effectiveness because 1,3-dichloropropene and chloropicrin are most effective in drier soils whereas metam works best in moist soils.
1, 3-Dichloropropene and Chloropicrin
It is important to use the appropriate amount of water so that the fumigant is evenly distributed throughout the target soil treatment zone. Drip fumigation with recommended amounts of irrigation water will provide good fumigant distribution in soil and reduce fumigant volatilization losses by increasing the amount of fumigant in the water phase and decreasing the total air space available for fumigant diffusion in soil.
- If too little water is used (less than 1.5 inches), the fumigant will be poorly distributed and more likely to volatilize, resulting in less effective control and lower strawberry yields. In addition, with insufficient water and without an emulsifier, fumigants such as 1,3-D or chloropicrin may precipitate in the irrigation pipelines if the concentrations exceed their solubility limits of 2,000 parts per million (ppm).
- However, using too much water may lower the fumigant concentration in the main line below 500 ppm, which can reduce fumigant effectiveness. Also, beds can lose their integrity and become unstable and collapse with excessive water application. Thus, bed stability may limit the volume or application rate of water.
Table 1 (below) lists the recommended amount of water needed to fumigate various soil types to a 24-inch soil depth. For example
- In a sandy loam soil, 2 inches of water in the bed is recommended to fumigate 24 inches deep. With two drip tapes, this provides a 40-inch lateral spread (10 inches on each side of a drip tape).
- If irrigation duration is limited, cutting back to 1.75 inches on sandy loam soils is often acceptable because fumigants move 3 to 5 inches beyond the wetting front and control should extend 2 feet deep. Although the fumigant will volatilize and move beyond the wetted zone, the best treatment appears to occur within the wetted area.
- If the water volume is cut back to the minimum recommendation of 1.5 inches for sandy loam soils, the soil profile will be wetted 18 inches deep with 6 to 8 inches of horizontal spread on both sides of each drip tape.
Metam Sodium or Metam Potassium
Metam sodium and metam potassium are water soluble and generate the active ingredient methyl isothiocyanate (MITC) after being applied to the soil. A minimum of one inch of water is recommended for the sequential application of metam to most soil types.
Drip Tape Flow Rate and Spacing
In drip fumigation, the rate of water flow and the spacing of drip tapes are critical to the even distribution of the fumigant throughout the field as well as in the soil treatment zone. While a water distribution uniformity of 90% is possible in a well designed and operated drip system, at least 80% is necessary for acceptable fumigation.
Drip tapes with a flow rate between 0.3 to 0.7 gallons per minute (gpm) per 100 feet are appropriate for most strawberry soils in California (see Table 1 below). Low-flow drip tape requires longer application time that may become inconvenient. Avoid high-flow drip tape (greater than 0.7 gpm/100 ft) if it causes any wetting of the furrows or runoff, or if it causes the beds to collapse. High-flow tape is not commonly used in California and is not recommended except for soils with high water permeability.
To achieve adequate water distribution uniformity, the pressure in the drip tape throughout the field should not vary more than 3 psi (e.g., from 6 to 9 psi). In addition, the system must be free of leaks and clogged emitters and be flushed and pressure tested before fumigation. It is imperative to use good quality irrigation components and drip tape. Leaks cause fumigant loss and possibly odor and emissions problems.
It may be necessary to reconfigure drip tape in order to obtain good water coverage across the soil bed. For most strawberry beds (sandy loam soils), one drip tape can cover up to 10 inches on each side. Therefore, two drip tapes are recommended for drip fumigation of most strawberry beds. In the two-row strawberry beds (narrow beds with two tapes near the center), spread the tapes as far apart as possible so that the edge of the bed is covered. In the four-row strawberry beds (wide beds with two tapes close to the shoulder), move the tapes a few inches towards the center to treat the middle of the bed. A third drip tape in the center may be needed if the bed top is wider than 40 inches. A third drip tape is also recommended in wide beds on sandy and loamy sand soils where limited lateral water movement may limit fumigant distribution.
Soil type | Volume of application water inches per acre (gallons)2 | Application time using 2 tapes (hours) | Comments | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Drip tape flow rate (gpm/100ft) | |||||||||||||||
0.20 | 0.34 | 0.50 | 0.67 | ||||||||||||
Fine sand and loamy fine sand | 1.6 (27,000) | 13.9 | 8.2 | 5.5 | 4.1 | Pre-irrigation with one inch of water is needed | |||||||||
Sandy loam and fine sandy loam | 2.0 (34,000) | 17.3 | 10.2 | 6.9 | 5.2 | Minimum of 1.5 inches is recommended | |||||||||
Sandy clay loam and loam | 2.6 (44,000) | 22.5 | 13.4 | 9.0 | NR | Split application may be required | |||||||||
Clay, clay loam, and silty clay loam | 3.2 (54,000) | 27.7 | 16.3 | 11.1 | NR | Soils not common in strawberry production |
1 | Application time and water volume based on 40-inch average bed width (64 inches center-to-center). |
2 | One broadcast acre-inch of water is about 27,000 gallons. One acre-inch of water for a 40-inch wide bed is about 17,000 gallons. |
NR | not recommended |
Determining the Fumigant Concentration in Irrigation Water
Fumigant concentration in the main line may vary from 500 to 1600 ppm, depending on on soil type, fumigant, and water application rate. Below 500 ppm, the efficacy of chloropicrin plus 1,3-dichloropropene (InLine) to control soilborne pathogens may be insufficient. Also, because the solubility of chloropicrin and 1,3-D in water is less than 2000 ppm at 68°F (20°C), exceeding 1500 ppm may result in precipitation of these fumigants in the irrigation pipelines and drip tape.
Fumigant concentration in water can be calculated as follows:
- Chloropicrin: ppm chloropicrin = 119,826 x (# pounds chloropicrin/# gallons water)
- InLine: ppm (chloropicrin / 1,3-D) = 87,872 x (# pounds InLine/# gallons water)
Table 2 shows chloropicrin concentrations as a function of application rate and water volume. A similar table can be prepared for 1,3-dichloropropene plus chloropicrin (InLine) (one gallon weighs 11.2 lb or 6.81 lb 1,3-D and 3.73 lb chloropicrin) but is not provided here because 1,3-dichloropropene requires a special permit to apply.
Other Important Calculations Needed for Drip Fumigation
- Determine the actual treated (bed) area, the total volume of water, and the weight of fumigants to be applied. Strawberry beds usually occupy 50 to 70% of the total area in the acre. Because only the beds are treated, this calculation can be important in determining how much fumigant is necessary for the treatment.
- Calculate the time required for application based on the flow rate of the drip tape.
Table 1 provides the application time for one particular type of bed configuration (40-inch wide with two drip tapes).
Chemigation Equipment for Drip Fumigation
The fumigant cylinders are pressurized with nitrogen gas and metered directly into the irrigation pipeline or manifold. The meter can be a precision needle valve and flow meter, a needle valve and a scale, or a computer-controlled positive displacement meter. Fumigants are injected at low-flow rates and accurate calibration of injection equipment is essential for proper application. Fumigant concentration in the main line may vary from 500 to 1600 ppm, depending on the soil, fumigant type, and water application rate. Refer to the pesticide label for appropriate concentration rates.
Good fumigant mixing with water in the irrigation pipelines is essential. Install a static mixing device after the point of injection to thoroughly mix fumigants with water before being distributed into the irrigation system laterals and drip tape.
The irrigation system must have a standard, single-check valve, a low-pressure drain, and a vacuum-relief valve (a "chemigation" valve) upstream from the injection point to prevent possible contamination of the water source by fumigants. The fumigant injector must be equipped with a check valve to prevent water from flowing back into the fumigant tank and an automatic quick-closing valve to stop fumigant injection when water flow is interrupted or loses pressure. The fumigant automatic shut-off valve can be electrically or hydraulically activated and should be normally closed at the injector. For more information on chemigation equipment, consult the agricultural commissioner office in your county.
Flushing the Pipeline Following Treatment
Many of the fumigants, including chloropicrin and 1,3-dichloropropene (InLine), can damage PVC if left in the pipelines. This does not occur during application of the diluted fumigants but can occur if the lines are not well flushed at the end of the application and the fumigant settles out and accumulates in low points of the distribution system. For this reason, it is critical to flush lines at the end of each application. The required amount of water needed to flush the system can be estimated as three times the volume of the mainline and laterals. Avoid excessive flushing because it will dilute the fumigants around the drip tape.
Safety Rule
Read and understand the fumigant label and follow county permit conditions before starting the fumigation. Know the symptoms and emergency treatments for exposure to the fumigants. Monitor the application system and the field during application.
Gallons water/acre | Pounds of chloropicrin (without emulsifier) | |||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
150 | 160 | 170 | 180 | 190 | 200 | 210 | 220 | 230 | 240 | 250 | 260 | 270 | 280 | 290 | 300 | |
19,000 | 946 | 1,009 | 1,072 | 1,135 | 1,198 | 1,261 | 1,324 | 1,387 | 1,451 | 1,514 | 1,577 | |||||
20,000 | 899 | 959 | 1,019 | 1,078 | 1,138 | 1,198 | 1,258 | 1,318 | 1,378 | 1,438 | 1,498 | 1,558 | ||||
21,000 | 856 | 913 | 970 | 1,027 | 1,084 | 1,141 | 1,198 | 1,255 | 1,312 | 1,369 | 1,427 | 1,484 | 1,541 | |||
22,000 | 817 | 871 | 926 | 980 | 1,035 | 1,089 | 1,144 | 1,198 | 1,253 | 1,307 | 1,362 | 1,416 | 1,471 | 1,525 | ||
23,000 | 781 | 834 | 886 | 938 | 990 | 1,042 | 1,094 | 1,146 | 1,198 | 1,250 | 1,302 | 1,355 | 1,407 | 1,459 | 1,511 | |
24,000 | 749 | 799 | 849 | 899 | 949 | 999 | 1,048 | 1,098 | 1,148 | 1,198 | 1,248 | 1,298 | 1,348 | 1,398 | 1,448 | 1,498 |
25,000 | 719 | 767 | 815 | 863 | 911 | 959 | 1,007 | 1,054 | 1,102 | 1,150 | 1,198 | 1,246 | 1,294 | 1,342 | 1,390 | 1,438 |
26,000 | 691 | 737 | 783 | 830 | 876 | 922 | 968 | 1,014 | 1,060 | 1,106 | 1,152 | 1,198 | 1,244 | 1,290 | 1,337 | 1,383 |
27,000 | 666 | 710 | 754 | 799 | 843 | 888 | 932 | 976 | 1,021 | 1,065 | 1,110 | 1,154 | 1,198 | 1,243 | 1,287 | 1,331 |
28,000 | 642 | 685 | 728 | 770 | 813 | 856 | 899 | 941 | 984 | 1,027 | 1,070 | 1,113 | 1,155 | 1,198 | 1,241 | 1,284 |
29,000 | 620 | 661 | 702 | 744 | 785 | 826 | 868 | 909 | 950 | 992 | 1,033 | 1,074 | 1,116 | 1,157 | 1,198 | 1,240 |
30,000 | 599 | 639 | 679 | 719 | 759 | 799 | 839 | 879 | 919 | 959 | 999 | 1,038 | 1,078 | 1,118 | 1,158 | 1,198 |
31,000 | 580 | 618 | 657 | 696 | 734 | 773 | 812 | 850 | 889 | 928 | 966 | 1,005 | 1,044 | 1,082 | 1,121 | 1,160 |
32,000 | 562 | 599 | 637 | 674 | 711 | 749 | 786 | 824 | 861 | 899 | 936 | 974 | 1,011 | 1,048 | 1,086 | 1,123 |
33,000 | 545 | 581 | 617 | 654 | 690 | 726 | 763 | 799 | 835 | 871 | 908 | 944 | 980 | 1,017 | 1,053 | 1,089 |
34,000 | 529 | 564 | 599 | 634 | 670 | 705 | 740 | 775 | 811 | 846 | 881 | 916 | 952 | 987 | 1,022 | 1,057 |
35,000 | 514 | 548 | 582 | 616 | 650 | 685 | 719 | 753 | 787 | 822 | 856 | 890 | 924 | 959 | 993 | 1,027 |
36,000 | 533 | 566 | 599 | 632 | 666 | 699 | 732 | 766 | 799 | 832 | 865 | 899 | 932 | 965 | 999 | |
37,000 | 518 | 551 | 583 | 615 | 648 | 680 | 712 | 745 | 777 | 810 | 842 | 874 | 907 | 939 | 972 | |
38,000 | 536 | 568 | 599 | 631 | 662 | 694 | 725 | 757 | 788 | 820 | 851 | 883 | 914 | 946 | ||
39,000 | 522 | 553 | 584 | 614 | 645 | 676 | 707 | 737 | 768 | 799 | 830 | 860 | 891 | 922 | ||
40,000 | 539 | 569 | 599 | 629 | 659 | 689 | 719 | 749 | 779 | 809 | 839 | 869 | 899 | |||
41,000 | 526 | 555 | 585 | 614 | 643 | 672 | 701 | 731 | 760 | 789 | 818 | 848 | 887 | |||
42,000 | 542 | 571 | 599 | 628 | 656 | 685 | 713 | 742 | 770 | 799 | 827 | 856 | ||||
43,000 | 529 | 557 | 585 | 613 | 641 | 669 | 697 | 725 | 752 | 780 | 808 | 836 | ||||
44,000 | 545 | 572 | 599 | 626 | 654 | 681 | 708 | 735 | 763 | 790 | 817 |
1 | ppm = parts per million |